After re-reading this multiple times, it seems you are talking about outbound provisioning for Office365.
You have to follow the guidelines for this. I believe that if you want things to work as expected (SSO, etc) the target domain has to be federated.
Aside from that, I can point you to (becasue there are moving parts to this)
- O365 techncenter: http://community.centrify.com/t5/TechCenter/Office-365-TechCenter/ba-p/25846
- O365 checklist: https://docs.centrify.com/en/centrify/appref/index.html#page/cloudhelp/o365/saas_appref_o365cklsts-o365.html
- o365 Help root page: https://docs.centrify.com/en/centrify/appref/index.html#page/cloudhelp%2Fo365%2Fsaas_appref_office365.html%23